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Dynamic Light Scattering

Particles suspended in liquids are in Brownian motion due to random collisions with solvent molecules. This motion causes the particles to diffuse through the medium. The diffusion coefficient, D, is inversely proportional to the particle size according to the Stokes-Einstein equation:

stokes einstein

Where D is the diffusion constant, kB the Boltzmann’s constant, T the absolute temperature, ƞ0 the viscosity, d the spherical particle diameter. Photon Correlation Spectroscopy (PCS), also referred to as dynamic light scattering, is a technique used to determine the diffusion coefficient of small particles in a liquid. The coefficient is determined by accurately measuring the light scattering intensity of the particles as a function of time. Photon correlation spectroscopy is a proven technique for particle size analysis of sub nano meter to a few micron particles.

Typical Experimental Results:

dynamic light scattering

Particle size analysis of a particle in solution

Applications:

Brownian Motion Contamination of Solution Effect of Additives
Electrophoretic Light Scattering Organic Mixtures Particle Suspensions
pH Analysis pH Titration Photo Correlation Spectroscopy
Polishing Slurries Sedimentation Temperature Testing


For more information please read our application notes.

Instruments: Beckman Coulter Delsa Nano C Particle Analyzer

particle sizeKey Specifications:

Measurable Size Range 0.6nm – 7µm
Concentration Range 0.001% - 40%
Maximum Heating Temp 90°C
Maximum Cooling Temp 15°C below ambient temp
pH Range 1-13
Scattering Angle 15°, 30°, 160°
Size Cell Sample Requirements 0.9mL
Flow Cell Sample Requirements 0.7mL
High Concentration Cell Sample Requirements 1mL
 

 

 


 
     

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